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Refinery Industry

Advanced Effluent Treatment Solutions for the Refinery Industry

Transform complex refinery wastewater streams into sustainable water assets through WTT's integrated treatment technologies and specialized solutions.

Critical Challenges

Critical Challenges in Refinery Wastewater Management

Complex multi-stream effluents, fluctuating compositions, and stringent regulations demand specialized treatment approaches for sustainable refinery operations.

Complex Multi-Stream Effluent

Desalter effluent (400-1000 mg L⁻¹ COD, up to 1000 mg L⁻¹ free hydrocarbons), sour water (300-12,000 ppm H₂S, 100-8,000 ppm NH₃), spent caustic, cooling tower blowdown, tank bottom draws requiring specialized treatment approaches.

Fluctuating Influent Quality

Variation in feedstock characteristics and production schedules lead to sudden shifts in wastewater composition, requiring adaptive treatment systems to maintain consistent performance.

Stringent Discharge Regulations

Stripped sour water targets H₂S < 10 ppm (often < 1 ppm), NH₃ < 100 ppm (often < 30 ppm), phenol up to 200 ppm with strict environmental compliance requirements.

Water Reuse Mandates

Regulatory and operational priority requiring advanced systems to meet stringent quality standards for reuse in boiler feed, cooling, and process applications.

High-Temperature Streams

Desalter effluent up to 300°F, sour water stripper overhead > 80°C to avoid ammonium bisulfide salt formation, requiring specialized heat-resistant treatment systems.

Operational Safety Concerns

Toxic H₂S evolution, handling of non-regenerable spent caustic, oil-water emulsion stability in desalters requiring intrinsically safe treatment approaches.

Technical Specifications

WTT Integrated Treatment Approach – Deep Technical View

Comprehensive treatment train designed specifically for complex refinery wastewater streams with guaranteed performance parameters.

Process StageCore Design FeaturesOperating WindowGuaranteed KPI
Rotary Brush ScreenerRemoves large solids, debris from incoming wastewaterMultiple stream handlingProtects downstream equipment from damage
API SeparatorThree-phase separation (oil, water, solids) with continuous skimming and scrapingGravity separation, handles high oil contentFree hydrocarbon removal, sludge handling
Dissolved Air FlotationNano-bubble generation, mechanical scraping, effective TSS & O&G removalCompact footprint designTSS and O&G load reduction for biological treatment
Equalization & NeutralizationFlow/pollutant load balancing, automated pH controlHandles fluctuating refinery compositionsStable feed to biological systems
Biological Oxidation SystemMicro-organisms metabolize organic compounds, aerated biological tank with DO controlExtended aeration for refinery loadsEfficient organic load reduction, controlled sludge handling
Membrane Bio-ReactorCeramic MBR with robust, long-lasting membranesCompact & modular designConsistent high-quality treated water, minimal maintenance
Membrane Filtration SystemsMF, UF, NF, RO technologies for progressive purificationTailored to specific separation needsUp to 99% dissolved salts removal (RO), selective ion removal
Sour Water TreatmentSteam stripping systems for H₂S and NH₃ removalSteam rate 60-300 kg steam/m³ feedH₂S < 1-10 ppm, NH₃ < 30-100 ppm
Spent Caustic TreatmentMedium pressure WAO technology operating ~13 barg, ~500°FCOD 10,000-100,000 mg L⁻¹ feedToxicity reduction, odor control, regulatory compliance
Utility Water TreatmentCustom-engineered systems for boiler feed, cooling, process waterSuspended solids removal, pH balancingConsistent water quality, equipment protection
Advanced Solutions

Advanced Refinery Treatment Solutions

Specialized technologies designed for complex refinery wastewater streams with guaranteed performance parameters and operational excellence.

Sour Water Stripping

Steam stripping systems operating 110-450 kPa with overhead > 80°C for H₂S and NH₃ removal from distillation units.

H₂S < 1 ppm, NH₃ < 30 ppm

Spent Caustic WAO

Medium pressure WAO technology operating ~13 barg, ~500°F for COD reduction and toxicity control in caustic treating systems.

COD 10,000-100,000 mg/L feed

Ceramic MBR

Robust ceramic membranes with 10+ year life, resistant to fouling and minimal maintenance for consistent high-quality treated water.

Flux 22-30 LMH @ 35°C

Multi-Stream Integration

Integrated approach handling desalter effluent, sour water, spent caustic, and cooling tower blowdown in complete treatment trains.

Complete treatment trains

Process Flow

Treatment Process Flow & Application Nodes

Integrated treatment chain optimized for multiple refinery wastewater streams with specialized recovery systems.

Complete Treatment Process:
Raw Refinery Effluent (Multiple Streams)
↳ Rotary Brush Screener
↳ API Separator (Oil/Water/Solids Separation)
↳ Dissolved Air Flotation
↳ Equalization & Neutralization
↳ Biological Oxidation System
↳ Membrane Bio-Reactor (Ceramic)
↳ Membrane Filtration (MF → UF → NF → RO)
Specialized Treatment Trains:
├─► Sour Water Stripping (Steam 60-300 kg/m³) → H₂S/NH₃ Recovery
├─► Spent Caustic WAO (13 barg, 500°F) → COD Reduction
└─► Utility Water Conditioning → Process Reuse
Recovered water for reuse → Boiler feed, cooling, irrigation, process makeup
Typical Installations:
Desalter effluent treatment – handles 400-1000 mg L⁻¹ COD, phenol extraction to crude for reuse
FCC sour water system – dedicated phenolic stripper, stripped water achieving H₂S < 1 ppm, NH₃ < 30 ppm
Ethylene plant spent caustic – WAO system processing high COD loads (10,000-100,000 mg L⁻¹)
Specialized Services

Specialized Refinery Services

Comprehensive suite of specialized treatment services designed for the unique challenges of refinery wastewater management.

Process Water Treatment

Handles crude desalting effluent, cooling tower blowdown, tank bottom draws, process unit effluents with specialized separation technologies.

Sour Water Treatment

Steam stripping systems operating 110-450 kPa, overhead &gt; 80°C, post-stripping biological polishing for H₂S and NH₃ removal.

Spent Caustic Treatment

Medium pressure WAO technology, neutralization systems, intrinsically safer than high-pressure alternatives for COD reduction.

Utility Water Treatment

Custom systems for boiler feedwater, cooling tower makeup, process water conditioning with ion exchange and RO technologies.

Sanitary Water Treatment

MBR technology with UV disinfection for domestic wastewater, pathogen-free reusable effluent for non-potable applications.

API Separator Systems

Three-phase separation with continuous oil skimming and sludge removal, handling high oil loads typical in refinery streams.

Performance Comparison

Why WTT Outperforms Conventional Refinery Treatment

Advanced integrated approach delivering superior performance across all critical refinery treatment parameters.

MetricWTTConventional Systems
Multi-stream handlingIntegrated approachSingle-stream focused
Sour water strippingH₂S &lt; 1 ppm, NH₃ &lt; 30 ppmH₂S &lt; 10 ppm, NH₃ &lt; 100 ppm
Spent caustic treatmentMedium pressure WAO (13 barg)High pressure (>25 barg) or disposal
Membrane durabilityCeramic 10+ yearsPolymeric 3-5 years
System integrationComplete treatment trainsIndividual unit focus
Automation levelFull SCADA, DO controlManual/limited
Reuse capabilityMultiple quality gradesSingle effluent quality
FAQ

Detailed Frequently Asked Questions

Comprehensive answers to technical questions about refinery wastewater treatment processes and technologies.

Transform Your Refinery Operations

Ready to Transform Your Refinery Wastewater Management?

Our refinery specialists will conduct a no-cost multi-stream effluent assessment and deliver a performance-guaranteed proposal.

WTT – engineering certainty in compliance, cost, and circularity for the global refining industry.